Sanstorm, you are right about the drivers. I unistalled the current drivers from device manager. Then unistalled Kies. Then uninstalled the USB drivers left behind in the Samsung install folder (where Kies also was). I then did a registry clean, restarted, and then installed Kies into a new Hard-drive partition just in case.
After the Kies re-install, I closed Kies, then plugged in my phone and waited. After a minute or so the following message showed up:
Do you have any ideas to get round this? Any idea if there is a version of this driver better suited to XP Professional SP3? Any help would be great.
EDIT: FINALLY I have connected with Kies and performed a sync! All I had to do in the end was Unmount the internal SD card, and it connected straight away. I read it has something to do with having too many .mp3 files stored on the SD card... which I probably have.
Anyway, finally fixed

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